CHARACTERIZATION OF PVA/CHITOSAN/ZEOLITE FILM SUBSTITUTED BY ION Ag+ AS ACTIVE PACKAGING

  • Dina Kartika Maharani Universitas Negeri Surabaya
  • Rizka Dwi Safitri Universitas Negeri Surabaya

Abstract

The need for fresh food continues to increase. Fresh food has a short shelf life. This can be overcome by active packaging containing antimicrobial substances. Zeolite is modified by ion exchange with silver, where silver acts as an antimicrobial agent. This study aims to study the changes in the mechanical properties of the PVA/chitosan mixture with the addition of zeolite-Ag compared to without the addition of zeolite-Ag. The variation in this study is the addition of zeolite-Ag to the PVA/CS composite, namely (0.025; 0.05; 0.1; 0.2)%. The films that have been made were analyzed in terms of mechanical properties, FTIR, and surface morphology microstructure. Composite films containing zeolite-Ag showed an increase in tensile strength and elasticity, where confirmed zeolite can be used as a reinforcing material in polymer matrices. The composite film with 0.025% zeolite-Ag content has a tensile strength value of 46.534 MPa, because zeolite-Ag can be homogeneously dispersed in the polymer matrix. FTIR analysis showed that the mixture of PVA and chitosan proved to be uniformly mixed. Morphological microstructural analysis showed homogeneous surface results, there was no visible appearance of zeolite-Ag aggregates on the PVA/CS film, whereas on films containing 0.025% zeolite-Ag there was a heterogeneous surface and the appearance of black circles indicating the presence of zeolite-Ag.

 

Key words: characterization, film composite, zeolit, silver

References

Boschetto, D. L., Lerin, L., Cansian, R., Pergher, S. B. C., & Di Luccio, M. 2012. Preparation and antimicrobial activity of polyethylene composite films with silver exchanged zeolite-Y. Chemical Engineering Journal, 204-206, 210–216.

Sofi, S. A., Singh, J., Rafiq, S., Ashraf, U., Dar, B. N., & Nayik, G. A. 2018. A Comprehensive Review on Antimicrobial Packaging and its Use in Food Packaging. Current Nutrition & Food Science, 14(4), 305–312.

Al-Tayyar, N. A., Youssef, A. M., & Al-Hindi, R. R. 2020. Antimicrobial packaging efficiency of ZnO-SiO2 nanocomposites infused into PVA/CS film for enhancing the shelf life of food products. Food Packaging and Shelf Life, 25, 100523.

Sharaf, O. M., Al-Gamal, M. S., Ibrahim, G. A., Dabiza, N. M., Salem, S. S., El-ssayad, M. F., & Youssef, A. M. 2019. Evaluation and Characterization of some protective culture Metabolites in free and nano-chitosan-loaded forms against Common Contaminants of Egyptian Cheese. Carbohydrate Polymers, 115094.

Youssef, H. F., El-Naggar, M. E., Fouda, F. K., & Youssef, A. M. 2019. Antimicrobial packaging film based on biodegradable CMC/PVA-zeolite doped with noble metal cations. Food Packaging and Shelf Life, 22, 100378.

Narasagoudr, S. S., Hegde, V. G., Chougale, R. B., Masti, S. P., & Dixit, S. 2020. Influence of boswellic acid on multifunctional properties of chitosan/poly (vinyl alcohol) films for active food packaging. International Journal of Biological Macromolecules.

Casariego, A., Souza, B. W. S., Vicente, A. A., Teixeira, J. A., Cruz, L., & Díaz, R. 2008. Chitosan coating surface properties as affected by plasticizer, surfactant and polymer concentrations in relation to the surface properties of tomato and carrot. Food Hydrocolloids, 22(8), 1452–1459.

Shiekh, R. A., Malik, M. A., Al-Thabaiti, S. A., & Shiekh, M. A. 2013. Chitosan as a Novel Edible Coating for Fresh Fruits. Food Science and Technology Research, 19(2), 139–155. doi:10.3136/fstr.19.139.

Higueras, L., López-Carballo, G., Hernández-Muñoz, P., Catalá, R., & Gavara, R. 2014. Antimicrobial packaging of chicken fillets based on the release of carvacrol from chitosan/cyclodextrin films. International Journal of Food Microbiology, 188, 53–59.

Caner, C., & Cansiz, O. 2006. Effectiveness of chitosan-based coating in improving shelf-life of eggs. Journal of the Science of Food and Agriculture, 87(2), 227–232.

No, H. K., Meyers, S. P., Prinyawiwatkul, W., & Xu, Z. 2007. Applications of Chitosan for Improvement of Quality and Shelf Life of Foods: A Review. Journal of Food Science, 72(5), R87–R100.

Casey, L. S., & Wilson, L. D. 2015. Investigation of Chitosan-PVA Composite Films and Their Adsorption Properties. Journal of Geoscience and Environment Protection, 03(02), 78–84.

Abdullah, Z. W., & Dong, Y. 2019. Biodegradable and Water Resistant Poly(vinyl) Alcohol (PVA)/Starch (ST)/Glycerol (GL)/Halloysite Nanotube (HNT) Nanocomposite Films for Sustainable Food Packaging. Frontiers in Materials, 6.

Youssef, A. M., Assem, F. M., Abdel-Aziz, M. E., Elaaser, M., Ibrahim, O. A., Mahmoud, M., & Abd El-Salam, M. H. 2019. Development of bionanocomposite materials and its use in coating of Ras cheese. Food Chemistry, 270, 467–475.

Tosheva, L., Belkhair, S., Gackowski, M., Malic, S., Al-Shanti, N., & Verran, J. 2017. Rapid screening of the antimicrobial efficacy of Ag zeolites. Colloids and Surfaces B: Biointerfaces, 157, 254–260

Chernousova, S., & Epple, M. 2012. Silver as Antibacterial Agent: Ion, Nanoparticle, and Metal. Angewandte Chemie International Edition, 52 (6), 1636–1653.

Ferreira, L., Fonseca, A. M., Botelho, G., Aguiar, C. A.-, & Neves, I. C. 2012. Antimicrobial activity of faujasite zeolites doped with silver. Microporous and Mesoporous Materials, 160, 126–132.

Cerrillo, J. L., Palomares, A. E., Rey, F., Valencia, S., Palou, L., & Pérez-Gago, M. B. 2017. Ag-zeolites as fungicidal material: Control of citrus green mold caused by Penicillium digitatum. Microporous and Mesoporous Materials, 254, 69–76.

Roy, A., Butola, B. S., & Joshi, M. 2017. Synthesis, characterization and antibacterial properties of novel nano-silver loaded acid activated montmorillonite. Applied Clay Science, 146, 278–285.

Osés, J., Fuentes, G., Palacio, J., Esparza, J., García, J., & Rodríguez, R. 2018. Antibacterial Functionalization of PVD Coatings on Ceramics. Coatings, 8(5), 197.

Cruz-Pacheco, A., Muñoz-Castiblanco, D., Gómez Cuaspud, J., Paredes-Madrid, L., Parra Vargas, C., Martínez Zambrano, J., & Palacio Gómez, C. 2019. Coating of Polyetheretherketone Films with Silver Nanoparticles by a Simple Chemical Reduction Method and Their Antibacterial Activity. Coatings, 9(2), 91.

ASTM D638-03. 2003. Standard Test Method For Plastics. ASTM International, west conshohcken, PA.

El-Hefian, E. A., Nasef, M. M., & Yahaya, A. H. 2011. Preparation and Characterization of Chitosan/Poly(Vinyl Alcohol) Blended Films: Mechanical, Thermal and Surface Investigations. E-Journal of Chemistry, 8(1), 91–96.

Ščetar, M., Siročić, A. P., Hrnjak-Murgić, Z., & Galić, K. 2013. Preparation and Properties of Low Density Polyethylene Film Modified by Zeolite and Nanoclay. Polymer-Plastics Technology and Engineering, 52(15), 1611–1620.

Choo, K., Ching, Y., Chuah, C., Julai, S., & Liou, N.-S. 2016. Preparation and Characterization of Polyvinyl Alcohol-Chitosan Composite Films Reinforced with Cellulose Nanofiber. Materials, 9(8), 644.

Published
2022-02-11
Section
Articles
Abstract Views: 193
PDF Downloads: 299