REVIEW: PRODUCTION OF BIODIESEL WITH TRANSESTERIFICATION METHOD USING CATALYST MADE FROM WASTE BONE
Abstract
Among various renewable energy sources, biodiesel is a promising candidate to replace fossil fuels. Biodiesel is produced from the transesterification reaction of oil or fat with alcohol. The transesterification reaction requires a suitable catalyst. There are two kinds of catalysts, namely homogeneous and heterogeneous catalysts. Heterogeneous catalysts have several advantages, including being easy to separate and can be reused without going through many processes. Currently, many natural materials are used as raw material for heterogeneous catalysts, such us bone. In this article, we will discuss the manufacture of biodiesel with a catalyst from various bone waste such as cow, goat, sheep, chicken, fish and ostrich bones. Based on the results of a review of several articles, it was known that the catalyst from bone which has the highest biodiesel yield comes from fish bone which is calcined at a temperature of 997.42 oC for 2 hours, the catalyst can produce a biodiesel yield of 97.73%. With the reaction conditions: ratio of moles of oil : methanol of 1 : 6.27, weight of the catalyst 1.01% of the mass of oil with a reaction that lasted for 5 hours at a temperature of 70 oC.
Key words: biodiesel, transesterification, catalyst, waste bone
References
J. Nisar, R. Razaq, M. Farooq, M. Iqbal, R. A. Khan, M. Sayed, A. Shah dan I. U. Rahman, “Enhanced Biodiesel Production From Jatropha Oil Using Calcined Waste Animal Bones as Catalyst,” Renewable Energy, vol. 101, pp. 111-119, 2017.
M. Farooq dan A. Ramli, “Biodiesel Production from Low FFA Waste Cooking Oil Using Heterogeneous Catalyst Derived from Chicken Bones,” Renewable Energy, vol. 76, pp. 362-368, 2015.
A. Pribadi, Kementerian Energi Dan Sumber Daya Mineral Siaran Pers Nomor: 028.Pers/04/SJI/2021, Jakarta: Kepala Biro Komunikasi, Layanan Informasi Publik, dan Kerja Sama Kementerian ESDM, 2021.
P. D. Patil dan S. Deng, “Optimization of Biodiesel Production From Edible and non-Edible Vegetable Oils,” Fuel, vol. 88, no. 7, pp. 1302-1306, 2009.
A. S. Chouhan dan A. K. Sarma, “Modern Heterogeneous Catalysts for Biodiesel Production: A Comprehensive Review,” Renewable and Sustainable Energy Reviews, vol. 15, p. 4378–4399, 2011.
S. H. Abdullah, N. H. Hanapi, A. Azid, R. Umar, H. Juahir, H. Khatoon dan A. Endut, “A Review of Biomass-Derived Heterogeneous Catalyst for a Sustainable Biodiesel Production,” Renewable and Sustainable Energy Reviews, vol. 70, pp. 1040-1051, 2017.
A. Obadiah, G. A. Swaroopa, S. V. Kumar, K. R. Jeganathan dan A. Ramasubbu, “Biodiesel Production From Palm Oil Using Calcined Waste Animal Bone as Catalyst,” Bioresource Technology, vol. 116, pp. 512-516, 2012.
Y. C. Sharma dan B. Singh, “Development of Biodiesel: Current Scenario,” Renewable and Sustainable Energy Reviews, vol. 3, no. 6-7, pp. 1646-1651, 2009.
D. M. Marinković, M. V. Stanković, A. V. Veličković, J. M. Avramović, M. R. Miladinović, O. O. Stamenković, V. B. Veljković dan D. M. Jovanović, “Calcium Oxide as a Promising Heterogeneous Catalyst for Biodiesel Production: Current State and Perspectives,” Renewable and Sustainable Energy Review, vol. 56, pp. 1387-1408, 2016.
Y. M. Sani, W. Daud dan A. A. Aziz, “Activity of Solid Acid Catalysts for Biodiesel Production: a Critical Review,” Applied Catalysis A: General, vol. 470, pp. 140-161, 2014.
S. M. Smith, C. Oopathum, V. Weeramongkhonlert, C. B. Smith, S. Chaveanghong, P. Ketwong dan S. Boonyuen, “Transesterification of Soybean Oil Using Bovine Bone Waste as New Catalyst,” Bioresource Technology, vol. 143, pp. 686-690, 2013.
J. Goli dan O. Sahu, “Development of Heterogeneous Alkali Catalyst From Waste Chicken Eggshell for Biodiesel Production,” Renewable Energy, vol. 128, pp. 142-154, 2018.
L. Yang, A. Zhang dan X. Zheng, “Shrimp Shell Catalyst for Biodiesel Production,” Energy & Fuels, vol. 23, no. 8, pp. 3859-3865, 2009.
S. Niju, K. M. Begum dan N. Anantharaman, “Enhancement of Biodiesel Synthesis Over Highly Active CaO Derived from Natural White Bivalve Clam Shell,” Arabian Journal of Chemistry, vol. 9, no. 5, pp. 633-639, 2016.
N. Nakatani, H. Takamori, K. Takeda dan H. Sakugawa, “Transesterification Of Soybean Oil Using Combusted Oyster Shell Waste As a Catalyst,” Bioresource Technology, vol. 100, no. 3, pp. 1510-1513, 2009.
F. D. Nurdyaningrum dan H. Nasrudin, “Pemurnian dan Karakterisasi Biodiesel Dari Minyak Biji Kelor (Moringa oleifera) dengan Menggunakan Adsorben Bentonit,” Unesa Journal of Chemistry, vol. 2, no. 1, 2013.
A. Krishnasamy dan K. R. Bukkarapu, “A Comprehensive Review of Biodiesel Property Prediction Models for Combustion Modeling Studies,” Fuel, vol. 302, 2021.
A. Marjaya, R. Achmad dan D. Murniati, “Efektivitas Berat Katalis dari Abu Kulit Kelapa pada Reaksi Transesterifikasi Minyak Sawit Menjadi Metil Ester,” Jurnal Kajian Ilmiah UBJ, vol. 15, no. 1, pp. 35-48, 2015.
P. L. Boey, G. P. Maniam dan S. Abd Hamid, “Performance of Calcium Oxide as a Heterogeneous Catalyst in Biodiesel Production: A Review,” Chemical Engineering Journal, vol. 168, no. 1, pp. 15-22, 2011.
L. T. Thanh, K. Okitsu, L. V. Boi dan Y. Maeda, “Catalytic Technologies for Biodiesel Fuel Production and Utilization of Glycerol: A Review,” Catalysts, vol. 2, no. 1, pp. 191-222, 2012.
V. Singh, L. Belova, B. Singh dan Y. C. Sharma, “Biodiesel Production Using a Novel Heterogeneous Catalyst, Magnesium Zirconate (Mg2Zr5O12): Process Optimization Through Response Surface Methodology (RSM),” Energy Conversion and Management, vol. 174, pp. 198-207, 2018.
Y. K. Salimi, N. I. Ischak dan Y. Ibrahim, “Karakterisasi Asam Lemak Hasil Hidrolisis Pada Minyak Biji Kelor (Moringa oleifera) Dengan Metode Kromatografi Gas-Spektroskopi Massa,” Jambura Journal of Chemistry, vol. 1, no. 1, pp. 6-14, 2019.
R. J. Fessenden dan J. S. Fessenden, Kimia Organik Edisi Ketiga Jilid 1, Jakarta: Erlangga, 1986.
I. M. Atadashi, M. K. Aroua, A. A. Aziz dan N. M. N. Sulaiman, “The Effects Of Catalysts In Biodiesel Production: A Review,” ournal of industrial and engineering chemistry, vol. 19, no. 1, pp. 14-26, 2013.
M. T. Haryono, S. Solihudin, E. Ernawati dan S. Pramana, “Limbah Cair Industri Minyak Goreng Sawit sebagai Bahan Baku Pembuatan Biodiesel,” EduChemia (Jurnal Kimia dan Pendidikan), vol. 4, no. 1, pp. 36-48, 2019.
W. T. Wahyuni dan M. Srimiati, “Pemanfaatan Ampas Tebu Untuk Meningkatkan Kualitas (Sifat Organoleptik, Parameter Oksidasi, Dan Profil Asam Lemak) Pada Minyak Jelantah,” Nutri Sains, vol. 2, no. 1, 2017.
A. Novilla, P. Nursidika dan W. Mahargyani, “Komposisi Asam Lemak Minyak Kelapa Murni (Virgin Coconut Oil) yang Berpotensi sebagai Anti Kandidiasis,” EduChemia (Jurnal Kimia dan Pendidikan), vol. 2, no. 2, pp. 161-173, 2017.
D. A. Setyawardhani, S. Distantina, H. Henfiana dan A. S. Dewi, “Pembuatan Biodiesel Dari Asam Lemak Jenuh Minyak Biji Karet,” dalam Seminar Rekayasa Kimia dan Proses, 2010.
H. Husin, M. Mahidin dan M. Marwan, “Studi Penggunaan Katalis Abu Sabut Kelapa, Abu Tandan Sawit Dan K2CO3 Untuk Konversi Minyak Jarak Menjadi Biodiesel,” Reaktor, vol. 13, no. 4, pp. 254-261, 2011.
J. V. Gerpen, “Biodiesel Processing and Production,” Fuel Processing Technology, vol. 86, no. 10, pp. 1097-1107, 2005.
E. Lotero, Y. Liu, D. E. Lopez, K. Suwannakarn, D. A. Bruce dan J. G. J. Goodwin, “Synthesis of Biodiesel via Acid Catalysis,” Industrial & Engineering Chemistry Research, vol. 44, no. 14, pp. 5353-5363, 2005.
E. Hambali, S. Mujdalifah, A. H. Tambunan, A. W. Pattiwiri dan R. Hendroko, Teknologi Bioenergi, Jakarta: Agro Media Pustaka, 2017.
R. Shan, L. Lu, Y. Shi, H. Yuan dan J. Shi, “Catalysts From Renewable Resources For Biodiesel Production,” Energy Conversion and Management, vol. 178, p. 277–289, 2018.
P. Purnami, I. N. G. Wardana dan K. Veronika, “Pengaruh Pengunaan Katalis Terhadap Laju Dan Efisiensi Pembentukan Hidrogen,” Jurnal Rekayasa Mesin, vol. 6, no. 1, pp. 51-59, 2015.
C. N. Kowthaman dan A. M. S. Varadappan, “Synthesis, Characterization, and Optimization of Schizochytrium Biodiesel Production,” International Journal of Energy Research, vol. 43, no. 8, pp. 3182-3200, 2019.
M. Raita, T. Laothanachareon, V. Champreda dan N. Laosiripojana, “Biocatalytic Esterification of Palm Oil Fatty Acids For Biodiesel Production Using Glycine-Based Cross-Linked Protein Coated Microcrystalline Lipase,” Journal of Molecular Catalysis B: Enzymatic, vol. 73, pp. 74-79, 2011.
A. K. Endalew, Y. Kiros dan R. Zanzi, “Inorganic Heterogeneous Catalysts For Biodiesel Production From Vegetable Oils,” Biomass And Bioenergy, vol. 35, no. 9, pp. 3787-3809, 2011.
S. Tang, H. Zhao, Z. Song dan O. Olubajo, “Glymes As Benign Co-Solvents For CaO-Catalyzed Transesterification Of Soybean Oil To Biodiesel,” Bioresource Technology, vol. 139, pp. 107-112, 2013.
M. Mohadesi, A. Gouran dan A. D. Dehnavi, “Biodiesel Production Using Low Cost Material as High Effective Catalyst in a Microreactor,” Energy, vol. 219, 2021.
M. A. Rahman, “Valorization of Harmful Algae E. Compressa for Biodiesel Production in Presence of Chicken Waste Derived Catalyst,” Renewable Energy, vol. 129, pp. 132-140, 2018.
R. Mohadi, A. Lesbani dan Y. Susie, “Preparasi dan Karakterisasi Kalsium Oksida (CaO) dari Tulang Ayam,” Chemistry Progress, vol. 6, no. 2, pp. 76-80, 2013.
R. Chakraborty dan D. RoyChowdhury, “Fish Bone Derived Natural Hydroxyapatite-Supported Copper Acid Catalyst: Taguchi Optimization of Semibatch Oleic Acid Esterification,” Chemical Engineering Journal, Vol. %1 dari %2215-216, pp. 491-499, 2013.
M. Boutinguiza, J. Pou, R. Comesaña, F. Lusquiños, A. D. Carlos dan B. Leon, “Biological Hydroxyapatite Obtained From Fish Bones,” Materials Science and Engineering: C, vol. 32, no. 3, pp. 478-486, 2012.
B. R. Sunil dan M. Jagannatham, “Producing Hydroxyapatite From Fish Bones By Heat Treatment,” Materials Letters, vol. 185, pp. 411-414, 2016.
P. V. Nam, N. Van Hoa dan T. S. Trung, “Properties of Hydroxyapatites Prepared From Different Fish Bones: A Comparative Study,” Ceramics International, vol. 45, no. 16, pp. 20141-20147, 2019.
M. Crucianelli, B. M. Bizzarri dan R. Saladino, “SBA-15 Anchored Metal Containing Catalysts in the Oxidative Desulfurization Process,” Catalysts, vol. 9, no. 12, 2019.
N. K. Al-Maram, Kajian Kalsinasi Tulang Sotong Berdasarkan Variasi Temperatur, Jakarta: UIN Syarif Hidayatullah, 2012.
I. Halikia, L. Zoumpoulakis, E. Christodoulou dan D. Prattis, “Kinetic Study of the Thermal Decomposition of Calcium Carbonate by Isothermal Methods of Analysis,” European Journal of Mineral Processing and Environmental Protection, vol. 1, no. 2, pp. 89-102, 2001.
Z. Yang dan W. Xie, “Soybean Oil Transesterification Over Zinc Oxide Modified With Alkali Earth Metals,” Fuel Processing Technology, vol. 88, no. 6, pp. 631-638, 2007.
M. AlSharifi dan H. Znad, “Transesterification of Waste Canola Oil by Lithium/Zinc Composite Supported on Waste Chicken Bone as an Effective Catalyst,” Renewable Energy, vol. 151, pp. 740-749, 2020.
A. A. Ayodeji, I. E. Blessing, B. Rasheed, O. E. Modupe, O. Ajibola, A. G. Oluwabunmi dan F. S. Ojo, “Production of Biodiesel From Soybean Oil Using Calcium Oxide and Cow Bone as Catalysts,” Materials Focus, vol. 7, no. 4, pp. 542-548, 2018.
P. Suwannasom, R. Sriraksa, P. Tansupo dan C. Ruangviriyachai, “Optimization of Biodiesel Production From Waste Cooking Oil Using Waste Bone as a catalyst,” Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. 38, no. 21, pp. 3221-3228, 2016.
C. H. Ali, A. H. Asif, T. Iqbal, A. S. Qureshi, M. A. Kazmi, S. Yasin, M. Danish dan B. Z. Mu, “Improved Transesterification of Waste Cooking Oil Into Biodiesel Using Calcined Goat Bone as a Catalyst,” Energy Sources, Part A: Recovery, Utilization, and Environmental Effect, vol. 40, no. 9, pp. 1076-1083, 2018.
T. T. Mamo dan Y. S. Mekonnen, “Microwave-Assisted Biodiesel Production from Microalgae, Scenedesmus Species, Using Goat Bone-Made Nano-Catalyst,” Applied Biochemistry and Biotechnology, vol. 190, no. 4, pp. 1147-1162, 2020.
R. Ghanei, R. K. Dermani, Y. Salehi dan M. Mohammadi, “Waste Animal Bone as Support for CaO Impregnation in Catalytic Biodiesel Production from Vegetable Oil,” Waste Biomass Valorization, vol. 7, no. 3, pp. 527-532, 2016.
R. Chakraborthy, S. Bepari dan A. Banerjee, “Application of Calcined Waste Fish (Labeo rohita) Scale as Low-Cost Heterogeneous Catalyst for Biodiesel Synthesis,” Bioresource Technology, vol. 102, no. 3, pp. 3610-3618, 2011.
H. M. Khan, T. Iqbal, C. H. Ali, A. Javaid dan I. I. Cheema, “Sustainable Biodiesel Production from Waste Cooking Oil Utilizing Waste Ostrich (Struthio camelus) Bones Derived Heterogeneous Catalyst,” Fuel, vol. 277, 2020.
F. Hussain, S. Alshahrani, M. M. Abbas, H. M. Khan, A. Jamil, H. Yaqoob, M. E. M. Soudagar, M. Imran, M. Ahmad dan M. Munir, “Waste Animal Bones as Catalysts for Biodiesel Production; A Mini Review,” Catalysts, vol. 11, no. 5, 2021.
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