PENGGUNAAN KITOSAN-POLIVINIL ALKOHOL (PVA)-KALSIUM KARBONAT SEBAGAI MATRIKS UREA SLOW-RELEASE FERTILIZER (SRF)
Isi Artikel Utama
Abstrak
Slow-release fertilizer merupakan metode efektif untuk meningkatkan efisiensi penyerapan pupuk, khususnya urea yang diperlukan tanaman pada fase awal pertumbuhan. Penelitian ini bertujuan mensintesis membran slow-release fertilizer (SRF) termodifikasi kitosan-Polivinil Alkohol (PVA) dengan variasi konsentrasi CaCO3 sebesar 0,01%, 0,05%, dan 0,1% (b/v). Karakterisasi uji swelling dan porositas, serta uji release urea selama 40 hari. Hasil menunjukkan bahwa peningkatan CaCO3 mempengaruhi struktur membran dan laju release urea. Membran C1 (0,01% CaCO3) memiliki porositas (74,52%) dan swelling (37,84%) tertinggi, menghasilkan release urea tercepat. Membran C2 (0,05% CaCO3) memberikan release tinggi dengan nilai porositas (21,33%) dan swelling (20.25%) lebih rendah, sehingga lebih stabil. Membran C3 (0,1% CaCO3) menunjukkan release urea paling rendah akibat agglomerasi CaCO3. Dengan demikian, konsentrasi CaCO3 sebesar 0,05% dinilai optimal untuk menghasilkan release urea yang tinggi namun terkendali dalam aplikasi pupuk berbasis membran kitosan–PVA.
Unduhan
Rincian Artikel

Artikel ini berlisensi Creative Commons Attribution 4.0 International License.
Referensi
Y. Hou, et al., "High-Strength, High-Water-Retention Hemicellulose-Based Hydrogel and Its Application in Urea Slow Release," International Journal of Molecular Science, 24(11), p. 9208, 2023.
[2] A. S.Gorung, J. J. Rondonuwu & T. Titah, "Pengaruh Pemberian Pupuk Urea Terhadap Pertumbuhan Tanaman Bayam (Amaranthus tricolor L) Pada Tanah Sawah Di Desa Ranoketang Atas," Soil Environmental, 22(1), pp. 12-16 2022.
[3] M. Fan, et al., "Effects of Combined Application of Slow-Release Nitrogen Fertilizer and Urea on Nitrogen Uptake, Utilization and Yield of Maize Under Two Tillage Methods," Scientific Reports, 15(5007), 2025.
[4] M. Shahzamani, et al., "Preparation and characterization of hydrogel nanocomposite based on nanocellulose and acrylic acid in the presence of urea," International Journal of Biological Macromolecules, Volume 147, pp. 187-193, 2020.
[5] R. Susanti, Rugayah, S. Widagdo, & D. H. Pangaribuan, "Pengaruh Dosis Pupuk Urea Terhadap Pertumbuhan Dan Hasil Tanaman Kailan (Brassica oleracea var. alboglabra)," Jurnal Agrotek tropika, 9(1), pp. 137-144, 2020.
[6] R. A. Lusiana, Khabibi, R. Nuryanto, & M. R. S. Al-Aziz, "Development and Characterization of a Chitosan and Polyvinyl Alcohol (CS/PVP)-Based Slow-Release Urea Fertilizer Membrane," Jurnal Kimia Sains dan Aplikasi, 27(10), pp. 470-476, 2024.
[7] R. A., Lusiana, et al., "Environmentally Friendly Slow-Release Urea Fertilizer Based on Modified Chitosan Membrane," Environmental Nanotechnology, Monitoring & Management, Volume 22, p. 100996, 2024.
[8] H. M. Ye, et al., "Degradable Polyester/Urea Inclusion Complex Applied as a Facile and Environment-Friendly Strategy for Slow-Release Fertilizer: Performance and Mechanism," 2020.
[9] T. D. S. Pereira, L. S. Fernandes, C. F. Souza, & R. Faez, "Biodegradable Enhanced Efficiency Fertilizer Based on Biopolymers/Zeolites Films, Assembly," Agricultural Science & Technology, 1(3), pp. 131-142, 2020, 2021.
[10] B. Beig, et al., "Coating Materials for Slow Release of Nitrogen from Urea Fertilizer: A review," Journal of Plant Nutrition, 43(10), pp. 1510-1533, 2020.
[11] W. Yuan, et al., "Preparation and Properties of a Novel Biodegradable Composite Hydrogel Derived from Gelatin/Chitosan and Polylactic Acid as Slow-Release N Fertilizer," Polymers, 15(997), 2023.
[12] D. Jahani, A. Nazari, J. Ghourbanpour, & A. Ameli, "Polyvinyl Alcohol/Calcium Carbonate Nanocomposites as E cient and Cost-Effective Cationic Dye Adsorbents," Polymers, 12(10), p. 2179, 2020.
[13] R. N., Annisa, R. A., Lusiana, Gunawan & H., Muhtar, "Optimization of Chitosan- Carboxymethyl Chitosan Membrane Modification with PVA to Increase Creatinine and Urea Permeation Efficiency," Jurnal Kimia Sains dan Aplikasi, 27(4), pp. 189-196, 2024.
[14] P. T. Vo, et al., "The nitrogen slow-release fertilizer based on urea incorporating chitosan and poly(vinyl alcohol) blend," Environmental Technology & Innovation, Volume 22, p. 101528, 2021.
[15] S. Chen, et al., "Preparation and Characterization of Slow-Release Fertilizer Encapsulated by Biochar-Based Waterborne Copolymers," Science of the Total Environment, Volume 615, pp. 431-437, 2018.
[16] A. M. Nurratri, et al., "Pembuatan dan Karakterisasi Membran Paduan Kitosan-Polietilen Glikol 6000," Open Journal Systems, 14(9), pp. 3261-3269, 2020.
[17] C. Sheng, Y. Zhou, X. Zhang, & G. Xue, "Mechanical, Thermal, and Swelling Properties of Cross-linked Hydrogels Based on Oxidized Cellulose Nanowhiskers and Chitosan/poly(vinyl alcohol) Blends," Fibers and Polymers, 19(10), pp. 2030-2038, 2018.
[18] R. Wang, L. Shi, & C.Y., Tang, "Inorganic Fillers in Mixed Matrix Membranes for Gas Separation," Journal of Applied Polymer Science, 135(5), p. 46108, 2018.